The most likely problem is a corrupt exe header/structure. Try redownloading, hopefully, from a different site. Or change your download manager.
The next likely problem is registry. Clean up your registry and try again.
The other possiblities are that you have a virus (only if all the exes refuse to start) or the exe is for a 64bit system.
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Winchester 3200+ @2,500MHz
LeadTek 7900GT VOLT MODDED @ 680 core, 1800 mem
2x1GB Transcend DDR400 @ DDR454 2.5,3,3,5,1T
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