The 10.10.xxx.xxx is a private IP addressing scheme. Which means that its for use in internal networks and not for use on the Internet. The range of private IP addresses for use in internal networks that are not visible to the computers on the Internet are:
10.0.0.0 - 10.255.255.255
172.16.0.0 - 172.31.255.255
192.168.0.0 - 192.168.255.255
EDIT: I had made a mistake earlier and thanks to digen, I have that corrected. I would also like to mention that in the absence of a DHCP server to assign addresses in a Windows environment, the IP addresses in the range of 169.254.0.0 -169.254.255.255 are used as Automatic Private IP Addressing or APIPA. Apologies to everyone!

(Thanks to digen)
However, the proxy/NAT server at your ISP notes the request your computer is making to thinkdigit.com (130.94.75.250) and then it uses its own IP address, the 202.172.xxx.xxx

N (where PN is the port number) to make a request to the thinkdigit.com site. When the site replies to your ISPs 202.172.xxx.xxx address, the NAT server recognizes that your computer on the internal network (10.10.xxx.xxx) made the request to thinkdigit.com and sends the data over to your computer. Hope you understood how this works!