It is very much possible.But there is a catch to it.Since you are behind a NAT device you got to configure port forwarding in that device to allow the remote connection[in this care your brother making a remote pc anywhere connection towards your end]
Depending upon the NAT device & its features you have to configure it accordingly so that remote requests will be allowed inbound into your internal pc which has got the client/server pc anywhere software installed.
With a little help from google I found that pcanywhere listens on TCP/UDP Ports 5631 and 5632.Also I learnt that the default ports can be changed with the help of the registry.
In case you need further help give us the NAT device brand & model no or in case its a multi-homed system give a few details about its architecture.
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