6600GT will perform better ofcourse! Btw, u can go for latest 8 series from Nvidia or HD3XXX series from ATi. Their price tags are also attractive these days. Anyways, ur choice.
Well, i would recommend atleast 350W PSU and that too from a reputed brand like Antec or CoolerMaster!
See, try plugging in the card. If u encounter any hangups or weird problems..

...that means, PSU is the culprit!