Even i had this problem when i wanted to put up a LAN card, when i put in the fourth slot. My system did not even boot, it hanged after the user selection menu.
This is what i did:
1. I removed my Modem (internal).
2. Fixed my LAN card in that PCI slot.
And it worked now. Just change the PCI slot as sourabh said.
But, u say u want already have a LAN card installed..., so i guess it may conflict with the other one, but i am not sure.
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