You could go for XFX 6600 256MB, it may cost u around 6-6.5K. As I have seen NVIDIA has better drivers support than ATI.
Haven't used ATI so no comment on that.
And certainly 6600 will always be better than 6200. If u can get a GAINWARD then get it without hesitation. With 6600 u could certainly play games at 1024*768 resolution.
If u could raise ur budget the buy leadtek 6600gt, a good value for money card that wouldn't be outdated soon. It may cost u around 9K.
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